MIL-101 promotes the efficient aerobic oxidative desulfurization of dibenzothiophenes
نویسندگان
چکیده
منابع مشابه
Catalytic properties of MIL-101.
A very high catalytic activity in the cyanosilylation reaction was observed for MIL-101, a chromium based metal-organic framework; moreover, MIL-101 is also a remarkably stable support for palladium in hydrogenation reactions, with significantly higher activity than e.g. palladium on activated carbon.
متن کاملSynergistic effects of encapsulated phthalocyanine complexes in MIL-101 for the selective aerobic oxidation of tetralin.
Metal phthalocyanine complexes encapsulated in MIL-101, and used as "ship-in-a-bottle" catalysts, show outstanding TONs in the aerobic oxidation of tetralin.
متن کاملCrystal-like microporous hybrid solid nanocast from Cr-MIL-101.
A crystal-like ordered microporous inorganic hybrid solid was prepared using silane functionalized Cr-MIL-101 (Si-MIL-101) as the precursor, via a surface coating reinforced framework strategy.
متن کاملSulfonyl chlorides as an efficient tool for the postsynthetic modification of Cr-MIL-101-SO3H and CAU-1-NH2.
Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO3H and CAU-1-NH2 have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound to the framework either by its N or its S atom.
متن کاملSynthesis and characterization of TBA-PV2Mo10@PVA as an efficient and reusable heterogeneous catalyst for oxidative desulfurization of gasoline
To prepare ultra-clean gasoline fuel, a new nanocomposite TBA-PV2Mo10@PVA was introduced as an efficient and green catalyst for oxidative desulfurization (ODS) process. The nanocomposite was successfully prepared by reaction of tetrabutylammonium bromide (TBA), H5PMo10V2O40, and poly vinyl alcohol (PVA) at room temperature via sol–gel method under oil-bath condition. The synthesized TBA-PV2Mo10...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Green Chemistry
سال: 2016
ISSN: 1463-9262,1463-9270
DOI: 10.1039/c5gc00862j